Spectroscopy of methylcyanodiacetylene revisited. Solid parahydrogen and solid neon matrix studies
| Autor: | Robert Kołos, Michał Turowski, Claudine Crépin, Jean-Claude Guillemin, Urszula Szczepaniak, Alejandro Gutiérrez-Quintanilla, Thomas Custer |
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| Přispěvatelé: | Institut des Sciences Moléculaires d'Orsay (ISMO), Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS), Polish Academy of Sciences (PAN), Universidad de La Habana [Cuba], Institut des Sciences Chimiques de Rennes (ISCR), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), This study was supported with the funds of the Polish National Science Centre, project No. 2011/03/B/ST4/02763, the French-Polish PICS project (2014–2016) and the RTRA Triangle de la Physique (2013-0436T REACMAQ)., Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
Physics::General Physics
Polyyne Analytical chemistry chemistry.chemical_element Infrared spectroscopy 010402 general chemistry Spin isomers of hydrogen 01 natural sciences Matrix isolation Spectral line Analytical Chemistry Inorganic Chemistry Neon Ultraviolet visible spectroscopy [CHIM]Chemical Sciences UV/Vis spectroscopy Spectroscopy 010405 organic chemistry Chemistry Phosphorescence Organic Chemistry 0104 chemical sciences IR spectroscopy |
| Zdroj: | Journal of Molecular Structure Journal of Molecular Structure, Elsevier, 2020, 1218, pp.128437. ⟨10.1016/j.molstruc.2020.128437⟩ Journal of Molecular Structure, 2020, 1218, pp.128437. ⟨10.1016/j.molstruc.2020.128437⟩ |
| ISSN: | 0022-2860 |
| DOI: | 10.1016/j.molstruc.2020.128437⟩ |
| Popis: | International audience; Electronic phosphorescence and infrared absorption spectra of methylcyanodiacetylene (CH3C5N) are revisited using matrix isolation in solid parahydrogen and neon. Band assignments previously found for Ar, Kr, Xe, and N2 low-temperature host media were updated, with certain ambiguous attributions being resolved. A combined analysis of both dispersed phosphorescence and phosphorescence excitation spectra observed in different environments provides a means to estimate the singlet-triplet separation for the gas-phase and pure solid compound, where phosphorescence could not be observed. |
| Databáze: | OpenAIRE |
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