Thermal decomposition of new chlorido(p-cymene) ruthenium(II) complexes containing N-alkylphenothiazines
| Autor: | Milena Krstić, Katalin Mészáros Szécsényi, Sofija P. Sovilj, Berta Barta Holló |
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| Rok vydání: | 2011 |
| Předmět: |
N-alkylphenothiazines
p-Cymene Chemistry Ruthenium(II) complexes N-alkylphenothiazines Thermal decomposition EGD Inorganic chemistry Thermal decomposition chemistry.chemical_element Atmospheric temperature range Ruthenium(II) complexes 010402 general chemistry Condensed Matter Physics 01 natural sciences 010406 physical chemistry 0104 chemical sciences Ruthenium Crystal chemistry.chemical_compound Thioridazine Hydrochloride Molecule Physical and Theoretical Chemistry EGD Single crystal Nuclear chemistry |
| Zdroj: | Journal of Thermal Analysis and Calorimetry |
| ISSN: | 1572-8943 1388-6150 |
| DOI: | 10.1007/s10973-011-1969-8 |
| Popis: | The thermal decomposition of [RuCl2(eta(6)-p-cymene)](2) (1) and its biologically active N-alkylphenothiazine compounds of composition L[RuCl3(eta(6)-p-cymene)] where L = CPH+ (2), TFH+center dot HCl (3), and TRH+ (4) (chlorpromazine hydrochloride, CP center dot HCl; trifluoperazine dihydrochloride, TF center dot 2HCl; and thioridazine hydrochloride, TR center dot HCl, respectively) has been studied. The crystal and molecular structure of compound 3 was determined earlier by single crystal X-ray diffraction analysis. The thermal data were collected by simultaneous TG/DSC measurements. For evolved gas detection, the qualitative reaction of chlorides with AgNO3 in an acidic solution was applied. The measurements were carried out in the temperature range to 700 A degrees C in nitrogen atmosphere. Compounds of L[RuCl3(eta(6)-p-cymene)] crystallize with water or water/2-propanole. On the basis of thermal data, the trend in the solvent bonding energies was assessed. |
| Databáze: | OpenAIRE |
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