Synthesis of anthracene end-capped poly(methyl methacrylate)s via atom transfer radical polymerization and its kinetic analyses
| Autor: | H Huiqi Zhang, L Bert Klumperman, Rob van der Linde |
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| Přispěvatelé: | Chemical Engineering and Chemistry, Materials and Interface Chemistry |
| Jazyk: | angličtina |
| Rok vydání: | 2002 |
| Předmět: |
Polymers and Plastics
Atom-transfer radical-polymerization Organic Chemistry Radical polymerization Solution polymerization Photochemistry Poly(methyl methacrylate) Inorganic Chemistry chemistry.chemical_compound End-group Reaction rate constant Polymerization chemistry visual_art Polymer chemistry Materials Chemistry visual_art.visual_art_medium Methyl methacrylate |
| Zdroj: | Macromolecules, 35(6), 2261-2267. American Chemical Society |
| ISSN: | 0024-9297 |
| DOI: | 10.1021/ma011575z |
| Popis: | The synthesis of anthracene end-capped poly(Me methacrylate)s via atom transfer radical polymn. (ATRP) and the kinetic analyses thereof are reported. Me methacrylate was polymd. in toluene at 90 DegC (or 60 DegC) via ATRP using 9-anthracene-methyl-2-bromo-isobutyrate as the initiator and CuBr/N-(n-hexyl)pyridylmethanimine as the catalyst. Anthracene end-capped polymers with predetd. mol. wts. and low polydispersity (PDI |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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