Synthesizing lead antimonate in ancient and modern opaque glass
| Autor: | I. Biron, Jakub Szlachetko, Jean Susini, Nicolas Menguy, Sophia Lahlil, Marine Cotte |
|---|---|
| Přispěvatelé: | Centre de recherche et de restauration des musées de France (C2RMF), Centre National de la Recherche Scientifique (CNRS)-Ministère de la Culture et de la Communication (MCC), European Synchrotron Radiation Facility (ESRF), Institute of Physics [Kielce], Jan Kochanowski University, Paul Scherrer Institute (PSI), Institut de minéralogie et de physique des milieux condensés (IMPMC), Université Pierre et Marie Curie - Paris 6 (UPMC)-IPG PARIS-Université Paris Diderot - Paris 7 (UPD7)-Centre National de la Recherche Scientifique (CNRS), Ministère de la Culture et de la Communication (MCC)-Centre National de la Recherche Scientifique (CNRS), Université Pierre et Marie Curie - Paris 6 (UPMC)-Université Paris Diderot - Paris 7 (UPD7)-Institut de Physique du Globe de Paris (IPG Paris)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: |
Lampworking
Materials science Opacity 010401 analytical chemistry Metallurgy Mineralogy 02 engineering and technology 021001 nanoscience & nanotechnology Microstructure 01 natural sciences 0104 chemical sciences Analytical Chemistry chemistry.chemical_compound Lead (geology) chemistry [PHYS.QPHY]Physics [physics]/Quantum Physics [quant-ph] Glass manufacturing 0210 nano-technology Chemical composition Single crystal Spectroscopy Antimonate |
| Zdroj: | Journal of Analytical Atomic Spectrometry Journal of Analytical Atomic Spectrometry, Royal Society of Chemistry, 2011, pp.1. ⟨10.1039/c0ja00251h⟩ Journal of Analytical Atomic Spectrometry, 2011, pp.1. ⟨10.1039/c0ja00251h⟩ |
| ISSN: | 0267-9477 1364-5544 |
| DOI: | 10.1039/c0ja00251h⟩ |
| Popis: | International audience; Through the study of lead antimonate based opacifiers in three opaque glass productions--Egyptian glass of the 18th dynasty (1570-1292 BC), Roman mosaic tesserae and beads from Aquilea and Rome (2nd c. BC-5th c. AD) and Nevers lampworking glass figures 18th c. AD)--this paper shows the evolution of lead antimonate production during different periods of History. We also show the necessity of using systematic micro-chemical analyses, with both high spatial and high energy resolution techniques to investigate these types of materials. The synchrotron-based m-XANES measurements combined with the microstructure observations (SEM and TEM), the chemical and structural analyses (EDX, WDS, m-Raman), is the first step to getting information on the raw materials used and the technological processes employed to produce lead antimonate. The heterogeneity from one sample to another but also within the same sample, and even further within a single crystal aggregate clearly shows that a production cannot be unambiguously associated to a single chemical composition. However, differences between the three productions are clearly highlighted and hypotheses about glass manufacturing are proposed. |
| Databáze: | OpenAIRE |
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