Hopping Conductance in Molecular Wires Exhibits a Large Heavy-Atom Kinetic Isotope Effect

Autor:	C. Daniel Frisbie, Quyen Van Nguyen
Rok vydání:	2021
Předmět:	Chemistry Conductance Charge (physics) General Chemistry 010402 general chemistry 01 natural sciences Biochemistry Catalysis 0104 chemical sciences Molecular wire Colloid and Surface Chemistry Chemical physics Intramolecular force Electrode Kinetic isotope effect Atom Molecule
Zdroj:	Journal of the American Chemical Society. 143:2638-2643
ISSN:	1520-5126 0002-7863
DOI:	10.1021/jacs.0c12244
Popis:	We report a large kinetic isotope effect (KIE) for intramolecular charge transport in π-conjugated oligophenyleneimine (OPI) molecules connected to Au electrodes. 13C and 15N substitution on the im...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c51c4ebe9812e75c086759896acfa9f7 https://doi.org/10.1021/jacs.0c12244 Zobrazit plný text záznamu