A New Lithium-Rich Zeolitic 10-MR Zincolithosilicate MZS-1 Hydrothermally Synthesized under High Pressure and Characterized by 3D Electron Diffraction
| Autor: | Gwladys Steciuk, Laurence Tortet, Hélène Pizzala, Jean-Louis Paillaud, Lukáš Palatinus, Wolfgang Hornfeck, Oliver Schäf |
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| Přispěvatelé: | Institute of Physics of the AS CR, Matériaux divisés, interfaces, réactivité, électrochimie (MADIREL), Aix Marseille Université (AMU)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut de Chimie Radicalaire (ICR), Institut de Science des Matériaux de Mulhouse (IS2M), Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Matériaux et Nanosciences Grand-Est (MNGE), Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Réseau nanophotonique et optique, Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Centre National de la Recherche Scientifique (CNRS), Centre National de la Recherche Scientifique (CNRS), Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA)), Université de Strasbourg (UNISTRA), Centre National de la Recherche Scientifique (CNRS)-Matériaux et nanosciences d'Alsace (FMNGE), Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Réseau nanophotonique et optique, Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA), Paillaud, Jean-Louis |
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_element
02 engineering and technology Lithium 010402 general chemistry 01 natural sciences Inorganic Chemistry Phase (matter) [CHIM.CRIS]Chemical Sciences/Cristallography [CHIM.CRIS] Chemical Sciences/Cristallography [CHIM.MATE] Chemical Sciences/Material chemistry Rietveld refinement Chemistry High pressure hydrothermal synthesis [CHIM.MATE]Chemical Sciences/Material chemistry Dynamical theory of diffraction Superstructures 021001 nanoscience & nanotechnology 0104 chemical sciences Crystallography Zinc Microcrystalline Electron diffraction Zeolites Crystallite 0210 nano-technology Superstructure (condensed matter) Electron diffraction tomography |
| Zdroj: | European Journal of Inorganic Chemistry European Journal of Inorganic Chemistry, 2021, 2021 (7), pp.628-638. ⟨10.1002/ejic.202000939⟩ European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2021, 2021 (7), pp.628-638. ⟨10.1002/ejic.202000939⟩ |
| ISSN: | 1434-1948 1099-0682 |
| Popis: | International audience; We report the structure of a new high lithium content zincolithosilicate (MZS‐1) obtained after hydrothermal treatment under high pressure from a glass precursor. After synthesis microcrystalline mixture of phases was obtained among which the main phase was unknown. Due to the sub micrometric size of the crystallites its structure was determined from precession‐assisted 3D electron diffraction measured at 100 K and refined using the dynamical theory of diffraction. More accurate lattice parameters are obtained from Rietveld refinement of synchrotron powder data collected at the ambient temperature. The characteristic framework is described at the ambient temperature using an average unit cell a0=8.57999(5) Å, b0=14.12332(8) Å, c0=4.96827(3) Å in the space group Ccc2. The structure of the new zeolitic 10‐membered ring zincosilicate with chemical formula per unit cell (SiO2)2Zn0.408LiO(OH)2(Li,H)2.184 (Z=4) is composed of undulated silicate layers made of fused 6‐membered rings connected via vertices of (Zn,Li)O4 tetrahedra. A weak superstructure doubling the a0 parameter is observed and is explained by a Zn/Li ordering within the (Zn,Li)O4 layers. |
| Databáze: | OpenAIRE |
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