Amorphization mechanism of SrIrO

Autor: Darrell G. Schlom, John W. Freeland, Dillon D. Fong, Shuo Chen, Ronghui Kou, Zhenxing Feng, Jin Suntivich, Guido Petretto, Cheng-Jun Sun, Gang Wan, Kyle Shen, J. Trey Diulus, Gregory S. Herman, Jingying Sun, Gian-Marco Rignanese, Geoffroy Hautier, Jianguo Wen, Ding-Yuan Kuo, Hua Zhou, Jocienne N. Nelson, Jan Kloppenburg, Yongqi Dong
Rok vydání: 2020
Předmět:
Zdroj: Science Advances
ISSN: 2375-2548
Popis: The transformation from crystalline SrIrO3 to active amorphous iridium oxide electrocatalyst occurs via the lattice oxygen redox.
The use of renewable electricity to prepare materials and fuels from abundant molecules offers a tantalizing opportunity to address concerns over energy and materials sustainability. The oxygen evolution reaction (OER) is integral to nearly all material and fuel electrosyntheses. However, very little is known about the structural evolution of the OER electrocatalyst, especially the amorphous layer that forms from the crystalline structure. Here, we investigate the interfacial transformation of the SrIrO3 OER electrocatalyst. The SrIrO3 amorphization is initiated by the lattice oxygen redox, a step that allows Sr2+ to diffuse and O2− to reorganize the SrIrO3 structure. This activation turns SrIrO3 into a highly disordered Ir octahedral network with Ir square-planar motif. The final SryIrOx exhibits a greater degree of disorder than IrOx made from other processing methods. Our results demonstrate that the structural reorganization facilitated by coupled ionic diffusions is essential to the disordered structure of the SrIrO3 electrocatalyst.
Databáze: OpenAIRE