Cyclopentadienone Derivative Dimers as Tunable Photoswitches
| Autor: | Yue-Hua Bao, Xinchang Wang, Zhihao Li, You-Zhen Zhuo, Xiao Tang, Lin-Lin Yang, Xiao-Yu Cao, Ru-Qiang Lu, Hang Qu |
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| Rok vydání: | 2021 |
| Předmět: |
Photoswitch
010405 organic chemistry Dimer Organic Chemistry Kinetics General Chemistry 010402 general chemistry Photochemistry 01 natural sciences Thermal kinetics Catalysis 0104 chemical sciences chemistry.chemical_compound Fatigue resistance chemistry Cyclopentadienone Photostationary state Derivative (chemistry) |
| Zdroj: | Chemistry – A European Journal. 27:7882-7886 |
| ISSN: | 1521-3765 0947-6539 |
| Popis: | A series of photoswitchable cyclopentadienone derivative dimers bearing bromo, thienyl, 4-(dimethylamino)phenyl, 3-pyridinyl, 4-nitrophenyl and cyano groups was designed and facilely synthesized. Their photoswitching properties such as the photoconversions in the photostationary state (PSS), the thermal kinetics and thermal half-lives of photoisomers were systematically investigated. These photoswitches show high fatigue resistance and large photoconversions in the PSS. This work proves that the photoswitching properties of photoswitches based on cyclopentadienone dimers can be tuned by substitution groups and also pave the way to functionalize the cyclopentadienone derivative dimer-based photoswitch, which is important for its future applications. |
| Databáze: | OpenAIRE |
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