Enantioselective, intermolecular [2+2] photocycloaddition reactions of 3-acetoxyquinolone: total synthesis of (−)-pinolinone
| Autor: | Christian Wiegand, Florian Mayr, Thorsten Bach |
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| Rok vydání: | 2013 |
| Předmět: |
Natural product
Cycloaddition Reaction Light Intermolecular force Metals and Alloys Enantioselective synthesis Total synthesis Stereoisomerism General Chemistry Quinolones Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials ddc chemistry.chemical_compound Acetals chemistry Yield (chemistry) Materials Chemistry Ceramics and Composites Organic chemistry |
| Popis: | The natural product (−)-pinolinone was synthesised via a concise route (six steps, 17% overall yield) from 3-acetoxyquinolone, employing an enantioselective intermolecular [2+2] photocycloaddition as the key step. |
| Databáze: | OpenAIRE |
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