Aqueous Chemistry of Transition Metals in Oxidation State (I) in Nanodroplets

Autor:	Vladimir E. Bondybey, Martin K. Beyer, Brigitte S. Fox, Iulia Balteanu, O. Petru Balaj
Rok vydání:	2002
Předmět:	Aqueous solution Chemistry Organic Chemistry Inorganic chemistry General Medicine General Chemistry Photochemistry Electrochemistry Redox Catalysis Solvent Solvation shell Transition metal Oxidation state Molecule Reactivity (chemistry)
Zdroj:	Chemistry - A European Journal. 8:5534-5540
ISSN:	1521-3765 0947-6539
Popis:	“Nanodroplets” consisting of a central ion surrounded by a solvation shell of water molecules provide an interesting medium for studies of aqueous transition-metal chemistry in the unusual oxidation state (I). While VI undergoes efficient, solvent shell dependent redox reactions to VII and VIII, the absence of any similar reactivity in aqueous CrI, MnI, FeI, CoI, NiI, and CuI clusters is explained by a rapid precipitation of the corresponding single monochloride molecules from the nanosolutions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c45a6249730aadddfc304b34d4fd8f99 https://doi.org/10.1002/1521-3765(20021216)8:24<5534::aid-chem5534>3.0.co Zobrazit plný text záznamu Plný text