A pyridyl-decorated MOF-505 analogue exhibiting hierarchical porosity, selective CO2 capture and catalytic capacity
| Autor: | Qin-Qin Dang, Yu-Fen Zhan, Xian-Ming Zhang, Li-Na Duan |
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| Rok vydání: | 2015 |
| Předmět: |
Models
Molecular Solvent molecule Pyridines High selectivity Phthalic Acids chemistry.chemical_element Carbon Dioxide Copper Catalysis Inorganic Chemistry Phthalic acid chemistry.chemical_compound Adsorption chemistry Polymer chemistry Organometallic Compounds Organic chemistry Porosity Group 2 organometallic chemistry |
| Zdroj: | Dalton Transactions. 44:20027-20031 |
| ISSN: | 1477-9234 1477-9226 |
| DOI: | 10.1039/c5dt01943e |
| Popis: | An expanded pyridyl-decorated MOF-505 analogue[Cu2(L)(H2O)2]·G(x) (H4L = 5,5'-(pyridine-2,5-diyl)diisophthalic acid, G = solvent molecule) has been solvothermally synthesized and reported. It exhibited rare hierarchical meso- and microporosity. With exposed unsaturated Cu(II) sites and Lewis basic pyridyl sites, the material shows both large CO2-uptake capacity (123.4 cm(3) g(-1) at 273 K, 1 bar) and high selectivity for CO2 over N2 (55.7) at 273 K. Furthermore, for the first time the compound has been exploited for its heterogeneous catalytic performance toward the cyanosilylation reaction under solvent-free conditions. The compound can be recycled up to five times with only a minor loss of activity. |
| Databáze: | OpenAIRE |
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