catena-Poly[[[diaqua-(tetra-methyl-ethylenediamine-κ(2) N,N')nickel(II)]-μ-sulfato-κ(2) O:O'] monohydrate]
| Autor: | Kurt Merzweiler, Guntram Schmidt |
|---|---|
| Rok vydání: | 2013 |
| Předmět: |
inorganic chemicals
Metal-Organic Papers biology Ligand Hydrogen bond chemistry.chemical_element Ethylenediamine General Chemistry Condensed Matter Physics biology.organism_classification Bioinformatics chemistry.chemical_compound Crystallography Nickel chemistry Atom Tetra General Materials Science Chelation Sulfate |
| Zdroj: | Acta Crystallographica Section E: Structure Reports |
| ISSN: | 1600-5368 |
| Popis: | The title compound, {[Ni(SO4)(C6H16N2)(H2O)2]·H2O} n , contains a Ni(II) atom that is coordinated nearly octa-hedrally by a chelating tetra-ethyl-enediamine (tmeda) ligand, two water mol-ecules in a cis arrangement and two O atoms of two sulfate anions in a trans arrangement. The sulfate anions act as μ2-bridging ligands leading to a chain structure of alternating NiO4N2 octa-hedra and SO4 tetra-hedra parallel to [001]. The polymeric chains are linked by O-H⋯O hydrogen bonds between coordinating water mol-ecules and sulfate anions to give double strands. There is a lattice water mol-ecule which is also involved in O-H⋯O hydrogen bonding between adjacent [Ni(SO4)(tmeda)(H2O)2] chains. |
| Databáze: | OpenAIRE |
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