Unsupported Nanoporous Platinum-Iron Bimetallic Catalyst for the Chemoselective Hydrogenation of Halonitrobenzenes to Haloanilines
| Autor: | Yanhui Li, Geng Yuxuan, Ming Bao, Zhanming Gao, Wei Zhang, Chen Chong, Tienan Jin, Xiujuan Feng, Wei Liu, Yantao Shi |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Materials science
010405 organic chemistry Nanoporous Inorganic chemistry Intermetallic Iron oxide chemistry.chemical_element 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis X-ray absorption fine structure chemistry.chemical_compound X-ray photoelectron spectroscopy chemistry General Materials Science Platinum Bimetallic strip |
| Zdroj: | ACS applied materialsinterfaces. 13(20) |
| ISSN: | 1944-8252 |
| Popis: | An unsupported nanoporous platinum-iron bimetallic catalyst (PtFeNPore) was prepared with an electrochemical dealloying technique. Its structure and composition were characterized through various measurement methods, such as X-ray absorption fine structure (XAFS) and X-ray photoelectron spectroscopy (XPS). An intermetallic compound and iron oxide species were both found in the PtFeNPore catalyst. The nanoporous structure and Lewis acidity (caused by iron oxide species) of the PtFeNPore catalyst resulted in superior catalytic activity and high selectivity. The PtFeNPore-catalyzed hydrogenation of various halonitrobenzenes proceeded successfully under mild reaction conditions and produced good to excellent yields of the corresponding haloanilines with high selectivity. PtFeNPore can be recycled through magnetic separation easily and reused five times without significant deactivation. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|