Na Storage Activity or Inertness of P-Configurations in N, P Dual-Doped Carbon Nanofibers: Bulk vs Surface

Autor: Shengyong Gao, Enhao Liu, Ning Wang, Jianqi Xu, Guixin Ma, Jisheng Zhou
Rok vydání: 2022
Předmět:
Zdroj: ACS Applied Materials & Interfaces. 14:56836-56846
ISSN: 1944-8252
1944-8244
DOI: 10.1021/acsami.2c17789
Popis: Heteroatom doping is an effective method to improve the electrochemical properties of hard carbon anodes for sodium-ion batteries. However, the different roles of surface and bulk heteroatoms in Na storage have not been explored much. Herein, N, P dual-doped carbon nanofibers (NP-CNFs) with high doping contents and low surface area are designed to clarify the above issue. It is confirmed that P plays a more crucial role in Na storage compared with N. In addition, surface and bulk P not only possess different configurations but also show distinct Na storage activity. There are only oxidized PO
Databáze: OpenAIRE