3,1,2,4-Benzothiaselenadiazine and related heterocycles: synthesis and transformation into Herz-type radicals

Autor:	Samat B. Zikirin, Alexander M. Genaev, Yulia M. Volkova, Andrey V. Zibarev, Irina Yu. Bagryanskaya, Alexander Makarov
Jazyk:	angličtina
Rok vydání:	2017
Předmět:	010405 organic chemistry Chemistry Radical General Chemistry 010402 general chemistry 01 natural sciences Transformation (music) 0104 chemical sciences law.invention халькоген-азотные кольца law Computational chemistry селенсодержащие соединения Electron paramagnetic resonance
Zdroj:	Mendeleev communications. 2017. Vol. 27, № 1. P. 19-22
Popis:	The archetypal 3,1,2,4-benzothiaselenadiazine, its 5- and 8-Me3Si derivatives and related dithiadiazine and trithiadiazepine were synthesized from 2-Me3SiC6H4N=S=NSiMe3 by the action of SeCl2, SeCl4, SCl2, and S2Cl2 and converted into persistent 2,1,3-benzothiaselenazolyl and 1,2,3-benzodithiazolyl radicals characterized by EPR spectroscopy and DFT calculations.
Databáze:	OpenAIRE
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