Growth condition dependence of unintentional oxygen incorporation in epitaxial GaN

Autor: F. Schubert, S. Schmult, Steffen Wirth, F. Zimmermann, Johannes Heitmann, Thomas Mikolajick
Jazyk: angličtina
Rok vydání: 2016
Předmět:
302 Crystallization / Heat treatment / Crystal growth
Materials science
Photoluminescence
Analytical chemistry
chemistry.chemical_element
100 Materials
Gallium nitride
02 engineering and technology
Epitaxy
01 natural sciences
Oxygen
Capacitance
oxygen incorporation
Article
gan
chemistry.chemical_compound
300 Processing / Synthesis and Recycling
Condensed Matter::Materials Science
Impurity
0103 physical sciences
General Materials Science
105 Low-Dimension (1D/2D) materials
Materials of engineering and construction. Mechanics of materials
103 Composites
500 Characterization
010302 applied physics
mbe
business.industry
Optical
Magnetic and Electronic Device Materials

505 Optical / Molecular spectroscopy
40 Optical
magnetic and electronic device materials

021001 nanoscience & nanotechnology
200 Applications
201 Electronics / Semiconductor / TCOs
501 Chemical analyses
chemistry
TA401-492
Optoelectronics
0210 nano-technology
business
Stoichiometry
TP248.13-248.65
Molecular beam epitaxy
Biotechnology
Zdroj: Science and Technology of Advanced Materials, Vol 17, Iss 1, Pp 239-243 (2016)
Science and Technology of Advanced Materials
ISSN: 1878-5514
1468-6996
Popis: Growth conditions have a tremendous impact on the unintentional background impurity concentration in gallium nitride (GaN) synthesized by molecular beam epitaxy and its resulting chemical and physical properties. In particular for oxygen identified as the dominant background impurity we demonstrate that under optimized growth stoichiometry the growth temperature is the key parameter to control its incorporation and that an increase by 55 °C leads to an oxygen reduction by one order of magnitude. Quantitatively this reduction and the resulting optical and electrical properties are analyzed by secondary ion mass spectroscopy, photoluminescence, capacitance versus voltage measurements, low temperature magneto-transport and parasitic current paths in lateral transistor test structures based on two-dimensional electron gases. At a growth temperature of 665 °C the residual charge carrier concentration is decreased to below 1015 cm−3, resulting in insulating behavior and thus making the material suitable for beyond state-of-the-art device applications.
Databáze: OpenAIRE