Extending the chemistry of carbones: P–N bond cleavage via an SN2′-like mechanism
| Autor: | Rakesh Ganguly, Milena Petković, Chitra Gurnani, Dragoslav Vidovic, Dušan Dimić, Nemanja Đorđević, Senthilkumar Muthaiah |
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| Přispěvatelé: | School of Physical and Mathematical Sciences |
| Rok vydání: | 2015 |
| Předmět: |
Chemistry
Ligand Stereochemistry Metals and Alloys General Chemistry Science::Chemistry::Organic chemistry::Carbanions [DRNTU] Catalysis 3. Good health Surfaces Coatings and Films Electronic Optical and Magnetic Materials Nucleophile Materials Chemistry Ceramics and Composites SN2 reaction Reactivity (chemistry) Bond cleavage Mechanism (sociology) |
| Zdroj: | Chemical Communications. 51:10762-10764 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c5cc03194j |
| Popis: | The reactivity of nucleophilic carbodiphosphorane (C(PPh3)2, 1) and carbodicarbene (C(C(NMe)2C6H4)2, 2) towards various dichlorophosphines has been explored. In most cases the expected carbone-for-chloride ligand exchange was observed. However, the use of MeN(PCl2)2 resulted in a unique P–N bond cleavage that, according to computational studies, occurred via an SN2′-like mechanism. Accepted version |
| Databáze: | OpenAIRE |
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