Unusual pre-oxidized polyacrylonitrile fibres behaviour against their activation with CO2: carbonization effect
| Autor: | Juan Alcañiz-Monge, M. Plaza-Recobert, G. Trautwein |
|---|---|
| Přispěvatelé: | Universidad de Alicante. Departamento de Química Inorgánica, Universidad de Alicante. Instituto Universitario de Materiales, Materiales Carbonosos y Medio Ambiente |
| Rok vydání: | 2016 |
| Předmět: |
Química Inorgánica
Carbonization General Chemical Engineering Reactivity CO2 activation Polyacrylonitrile 02 engineering and technology Surfaces and Interfaces General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Activated carbon fibres 01 natural sciences 0104 chemical sciences chemistry.chemical_compound Adsorption chemistry Microporosity Polymer chemistry Reactivity (chemistry) Polyacrylonitrile carbon fibres 0210 nano-technology Porosity |
| Zdroj: | RUA. Repositorio Institucional de la Universidad de Alicante Universidad de Alicante (UA) |
| ISSN: | 1572-8757 0929-5607 |
| DOI: | 10.1007/s10450-016-9757-1 |
| Popis: | The CF-PAN activation process with CO2 has been analysed. Activation of CF-PAN with CO2 leads to unusual results both, activation percentage evolution over the time and generated porosity development. In the explanation has been highlighted the role of the carbonization step in the CF-PAN activation process. The analysed results point to the fact that part of the released nitrogen-containing compounds during PANOX fibres carbonization are deposited on the CF surface, which affects to carbonized PAN fibres, decreasing actives sites, or acting as inhibitors of the gasification reaction. The authors thank the Generalitat Valenciana and FEDER (PROMETEO2/2014/010), and MICINN and Plan E (CTQ2012-31762) for the financial support. |
| Databáze: | OpenAIRE |
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