Oxazolidinone-promoted, torquoselective Nazarov cyclizations

Autor:	Jonathan M. White, Daniel J. Kerr, Jason Hugh Chaplin, Bernard L. Flynn, Michael Miletic
Rok vydání:	2012
Předmět:	Cyclopentanes Molecular Structure Chemistry Organic Chemistry Stereoisomerism Biochemistry Catalysis Cyclization Molecule Organic chemistry Physical and Theoretical Chemistry Oxazolidinones
Zdroj:	Organic letters. 14(7)
ISSN:	1523-7052
Popis:	Oxazolidinones are powerful promoters of the Nazarov reaction, enabling the cyclization of conventionally resistant substrates to be achieved under mild conditions. They exert excellent regio- and torquoselective control in both the conventional Nazarov reaction giving cyclopentenones and in the "interrupted" Nazarov reaction, giving more highly substituted multistereocenter containing products.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c2fef0f0ba452d3fd7dbc30a2e2e7de4 https://pubmed.ncbi.nlm.nih.gov/22455473 Zobrazit plný text záznamu