Crystal structure and Hirshfeld surface analysis of (E)-3-(benzylideneamino)-5-phenylthiazolidin-2-iminium bromide
| Autor: | Abel M. Maharramov, Gulnara Sh. Duruskari, Gunay Z. Mammadova, Mehmet Akkurt, Taras Chyrka |
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| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
crystal structure Crystallography Hydrogen bond Iminium Salt (chemistry) General Chemistry Crystal structure Condensed Matter::Mesoscopic Systems and Quantum Hall Effect Condensed Matter Physics Ring (chemistry) Crystal chemistry.chemical_compound chemistry Bromide QD901-999 Atom charge assisted hydrogen bonding hirshfeld surface analysis thiazolidine ring envelope conformation General Materials Science |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 76, Iss 3, Pp 427-431 (2020) |
| ISSN: | 2056-9890 |
| Popis: | The central thiazolidine ring of the title salt, C16H16N3S+center dot Br-, adopts an envelope conformation, with the C atom bearing the phenyl ring as the flap atom. In the crystal, the cations and anions are linked by N-H center dot center dot center dot Br hydrogen bonds, forming chains parallel to the b-axis direction. Hirshfeld surface analysis and two-dimensional fingerprint plots indicate that the most important contributions to the crystal packing are from H center dot center dot center dot H (46.4%), C center dot center dot center dot H/H center dot center dot center dot C (18.6%) and H center dot center dot center dot Br/Br center dot center dot center dot H (17.5%) interactions. |
| Databáze: | OpenAIRE |
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