Solvent effects on the spectroscopic properties of 4-hexylresorcinol
| Autor: | María Isela Gutiérrez, Susana Risso, Sonia Patricia Olivares |
|---|---|
| Rok vydání: | 2008 |
| Předmět: |
Physics::Biological Physics
Quantitative Biology::Biomolecules Molecular Structure Chemistry Hexylresorcinol Analytical chemistry Quantum yield Fluorescence Atomic and Molecular Physics and Optics Analytical Chemistry Condensed Matter::Soft Condensed Matter Solvent Spectrophotometry Solvents Molecule Emission spectrum Physics::Chemical Physics Absorption (chemistry) Solvent effects Spectroscopy Instrumentation |
| Zdroj: | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 71:336-339 |
| ISSN: | 1386-1425 |
| DOI: | 10.1016/j.saa.2007.12.037 |
| Popis: | A study was made on the spectroscopic properties of 4-hexylresorcinol (4HR) in several solvents at room temperature. Absorption and emission spectra were slightly affected by solvent polarity. Stokes' shifts were small (approximately 3000 cm(-1)) and the fluorescence quantum yields varied between 0.05 and 0.68, depending on the solvent. The spectral shifts were correlated with different solvent scales. Multiple regression analysis indicates that both non-specific solute-solvent interactions as well as specific solute-solvent interactions (such as hydrogen bonding) play an important role in the position of the Stokes' shift and on the fluorescence quantum yield in the solvents under study. |
| Databáze: | OpenAIRE |
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