Rational design, structure properties, and synthesis strategies of dual-pore covalent organic frameworks (COFs) for potent applications: A review

Autor: Shilpa Patial, Vatika Soni, Abhinandan Kumar, Pankaj Raizada, Tansir Ahamad, Xuan Minh Pham, Quyet Van Le, Van-Huy Nguyen, Sourbh Thakur, Pardeep Singh
Rok vydání: 2023
Předmět:
Zdroj: Environmental Research. 218:114982
ISSN: 0013-9351
DOI: 10.1016/j.envres.2022.114982
Popis: Dual-pore covalent organic frameworks (COFs) offer a molecular scaffold for introducing building blocks into periodically organized polygonal skeletons to produce fascinating structural features. The rapid development of this material has attracted intensive interest from researchers with diverse expertise. This review selects the leading scientific findings about dual-pore COFs and highlights their functions and perspectives on design, structure properties, and synthesis strategies. Dual-pore COFs, as newly hetero-pore COFs by integrating particular pores into one polygonal skeleton, have been compared to conventional COFs. Dual-pore COFs display hierarchical/heterogeneous porosities and homogeneous porosity, which endow them with exceptional features involving mass diffusion, charge transfer, and large surface area with abundant active sites. Additionally, the strategic dual-pore design by opting for different approaches, such as integration of [D
Databáze: OpenAIRE