Hot electron-induced electrogenerated chemiluminescence of Ru(bpy)(3)(2+) chelate at a pointed active metal cathode in fully aqueous solutions
| Autor: | Päivi Kuosmanen, Sakari Kulmala, Kalle Salminen, Matti Pusa, Timo Ala-Kleme |
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| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
Tris
General Chemical Engineering Inorganic chemistry ta221 chemistry.chemical_element 02 engineering and technology 010402 general chemistry 01 natural sciences Analytical Chemistry law.invention Metal chemistry.chemical_compound DNA probe assay law Electrochemistry Electrochemiluminescence ta116 Chemiluminescence Immunoassay Aqueous solution ta114 Bioaffinity assay ta1182 021001 nanoscience & nanotechnology Cathode 0104 chemical sciences Ruthenium Field electron emission chemistry visual_art visual_art.visual_art_medium Hot electron 0210 nano-technology |
| Zdroj: | Journal of Electroanalytical Chemistry. 783:63-67 |
| ISSN: | 1572-6657 |
| Popis: | Tris(2,2′-bipyridine)ruthenium(II) chelate exhibits strong electrogenerated chemiluminescence during cathodic high-voltage pulse-polarization of pointed Pt electrode in aqueous solutions. The present method is based on a field emission or other type of tunnel emission of hot electrons into an aqueous electrolyte solution. The method allows the detection of tris(2,2′-bipyridine)ruthenium(II) and its derivatives below nanomolar concentration levels and yields linear log-log calibration plots spanning several orders of magnitude of concentration. |
| Databáze: | OpenAIRE |
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