Nonmetal catalyzed insertion reactions of diazocarbonyls to acid derivatives in fluorinated alcohols
| Autor: | Kaouther Azzouzi-Zriba, Danièle Bonnet-Delpon, Benoit Crousse, Lidia Dumitrescu |
|---|---|
| Rok vydání: | 2011 |
| Předmět: |
inorganic chemicals
Alkanesulfonates Halogenation Molecular Structure Organic Chemistry Diazonium Compounds Ketones Biochemistry Phosphonate Combinatorial chemistry Boronic Acids Catalysis Organophosphates chemistry.chemical_compound Sulfonate chemistry Nonmetal Insertion reaction Alcohols Combinatorial Chemistry Techniques Metal catalyst Physical and Theoretical Chemistry |
| Zdroj: | Organic letters. 13(4) |
| ISSN: | 1523-7052 |
| Popis: | The insertion reaction of diazocarbonyls to acids could be performed smoothly in fluorinated alcohols in the absence of metal catalyst. This new procedure allowed the chemoselective preparation of various functionalized compounds such as acyloxyesters, depsipeptides, and sulfonate, phosphonate, or boronate derivatives. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|