Hydroarylation of N ‐Allenyl Derivatives Catalyzed by Copper
| Autor: | Florian Monnier, Lucas Pagès, Marc Taillefer, Racha Abed Ali Abdine |
|---|---|
| Přispěvatelé: | Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC) |
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
Allylic rearrangement
arenes hydroarylation chemistry.chemical_element Homogeneous catalysis 010402 general chemistry 01 natural sciences Medicinal chemistry Catalysis chemistry.chemical_compound Nucleophile Physical and Theoretical Chemistry 010405 organic chemistry [CHIM.ORGA]Chemical Sciences/Organic chemistry Aryl Organic Chemistry Intermolecular force [CHIM.CATA]Chemical Sciences/Catalysis Copper homogeneous catalysis 0104 chemical sciences chemistry allenes copper Stereoselectivity allylic compounds |
| Zdroj: | European Journal of Organic Chemistry European Journal of Organic Chemistry, Wiley-VCH Verlag, 2020, 2020 (48), pp.7466-7469. ⟨10.1002/ejoc.202001333⟩ |
| ISSN: | 1434-193X 1099-0690 |
| DOI: | 10.1002/ejoc.202001333⟩ |
| Popis: | A simple copper catalytic system was used to perform the addition of (hetero)aryl nucleophiles to N-allenyl derivatives. This intermolecular C-C bond formation occurs with both complete regio- and stereoselectivity to afford the linear (E) allylic product with moderate to excellent yields. This atom economical method is the first example of hydroarylation of allenes catalyzed by copper. |
| Databáze: | OpenAIRE |
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