Enhanced UV and ethanol vapour sensing of a single 3-D ZnO tetrapod alloyed with Fe2O3 nanoparticles
| Autor: | Vasile Postica, Nora H. de Leeuw, Abhishek Kumar Mishra, Jorit Gröttrup, Rainer Adelung, Oleg Lupan |
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| Rok vydání: | 2017 |
| Předmět: |
Materials science
Fabrication Oxide chemistry.chemical_element Nanotechnology 02 engineering and technology Zinc 010402 general chemistry medicine.disease_cause 01 natural sciences chemistry.chemical_compound Nanosensor Nano Materials Chemistry medicine QD Electrical and Electronic Engineering Instrumentation Doping Metals and Alloys 021001 nanoscience & nanotechnology Condensed Matter Physics Microstructure 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry 0210 nano-technology Ultraviolet |
| Zdroj: | Sensors and Actuators B: Chemical. 245:448-461 |
| ISSN: | 0925-4005 |
| DOI: | 10.1016/j.snb.2017.01.107 |
| Popis: | Fabrication of multifunctional devices based on nano- and microstructures of a single semiconducting oxide is an important step for a better understanding of their maximum sensing properties and the base for the development of bottom-up nanotechnologies. In this work we have fabricated, for the first time devices based on a single or two interconnected ZnO tetrapods (T), doped with Fe and alloyed with Fe2O3 nanoparticles (NPs) and microparticles (MPs) in order to improve their sensing properties towards ultraviolet (UV) sensing and ethanol vapour (EtOH). Compared to pristine ZnO-T improved UV and gas sensing properties of Fe-doped ZnO-T were observed. By Fe2O3-alloying of Fe-doped ZnO-T further improvement in sensing properties was obtained with a reduced influence of the relative humidity (RH) on the sensing response. A gas sensing mechanism was proposed and discussed in detail based on the alloyed Fe2O3 NPs and MPs. The results presented here demonstrate the efficiency of doping and alloying of single ZnO microstructures with other semiconducting oxides to improve their sensing properties, including the decrease in influence of RH on the gas response and the rapidity of the sensors. |
| Databáze: | OpenAIRE |
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