Studies on the synthesis of valienamine and 1-epi-valienamine starting from D-glucose or L-sorbose

Autor:	Ian Cumpstey, Riccardo Cribiu, Sayeh Erfan, Sebastian Gehrke
Rok vydání:	2008
Předmět:	Early introduction Chemistry Valienamine Organic Chemistry Stereoisomerism Hexosamines General Medicine Metathesis Sorbose Biochemistry Analytical Chemistry chemistry.chemical_compound Ring-closing metathesis Glucose D-Glucose Cyclohexenes Organic chemistry
Zdroj:	Carbohydrate research. 343(10-11)
ISSN:	0008-6215
Popis:	Two synthetic routes to a carbocyclic precursor to valienamine are reported, starting from either D-glucose or L-sorbose and using ring-closing metathesis as a key step. A low-yielding synthesis of 1-epi-valienamine is reported. Results from an abortive third possible route to valienamine based on an early introduction of nitrogen are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c1db24f1afba0d5483623664d232c6dc https://pubmed.ncbi.nlm.nih.gov/18468588 Zobrazit plný text záznamu Full Text from ScienceDirect