Novel Hydrocarbyl and Hydride Compounds of Bis-pentamethylcyclopentadienylcerium (III)

Autor:	Jaap Renkema, Jan H. Teuben
Přispěvatelé:	Stratingh Institute of Chemistry, Molecular Inorganic Chemistry
Jazyk:	angličtina
Rok vydání:	1986
Předmět:	Cerium Hydride Chemistry Polymer chemistry chemistry.chemical_element Organic chemistry General Chemistry Lewis acids and bases
Zdroj:	Recueil des Travaux Chimiques des Pays-Bas-Journal of the Royal Netherlands Chemical Society, 105(7-8), 241-242. ELSEVIER SCIENCE BV
ISSN:	0165-0513
Popis:	The synthesis of novel hydrocarbyl and hydride cerium complexes Cp*2CeCH(SiMe3)2 (Cp* = η5-C5Me5) and (Cp*2CeH)2 is reported. The hydrocarbyl shows Lewis acid properties and complexes salts like LiCl. The hydride is exceptionally reactive and activates P-C bonds in PMe3.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c1dafe02abaf1555cce9df0ae8b29b91 https://research.rug.nl/en/publications/f74e82a3-4846-4106-a954-d58632898b22 Zobrazit plný text záznamu Plný text