Substitution of β-nitrostyrenes by electrophilic carbon-centered radicals
| Autor: | Rymundo Cruz-Almanza, Alejandro Garcı́a-Torres, Luis D. Miranda |
|---|---|
| Rok vydání: | 2004 |
| Předmět: |
chemistry.chemical_classification
Substitution reaction Radical-nucleophilic aromatic substitution Radical substitution Chemistry Alkene Radical Substitution (logic) Organic Chemistry General Medicine Carbon centered radicals Biochemistry Peroxide Medicinal chemistry chemistry.chemical_compound Yield (chemistry) Drug Discovery Electrophile Organic chemistry Free-radical addition |
| Zdroj: | Tetrahedron Letters. 45:2085-2088 |
| ISSN: | 0040-4039 |
| DOI: | 10.1016/j.tetlet.2004.01.061 |
| Popis: | Various trans -β-alkylstyrenes (55–90% yield) were isolated from the free radical addition/elimination process of α-iodocarboxylic acid derivatives with β-nitrostyrenes using dilauroyl peroxide as initiator. The corresponding xanthates give low yields of the alkene under similar conditions. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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