Bis(2-methylpyridinium) tetrachloridocuprate(II): synthesis, structure and Hirshfeld surface analysis
| Autor: | Tahir Mehmood, J Prakasha Reddy, Rajesh S Bhosale |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
crystal structure
Crystallography biology Hydrogen bond Chemistry inorganic supramolecular chemistry General Chemistry Crystal structure Condensed Matter Physics biology.organism_classification hydrogen bonding inorganic supramolecular chemistry Research Communications Ion Copper atom chemistry.chemical_compound QD901-999 Tetra General Materials Science Cuprate Pyridinium 2-picoline complex Monoclinic crystal system |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 77, Iss 7, Pp 726-729 (2021) Acta Crystallographica Section E: Crystallographic Communications |
| ISSN: | 2056-9890 |
| Popis: | The structure of bis(2-methylpyridinium) tetrachlorocuprate(II) is characterized by layers formed by [C6H8N]+ and [CuCl4]2– connected through N—H⋯Cl and C—H(phenyl)⋯Cl interactions. The layers are further connected by C—H(methyl)⋯Cl interactions. The title compound, (C6H8N)2[CuCl4], crystallizes in the monoclinic space group I2/c. The coordination around the copper atom is a distorted tetrahedron. The 2-methylpyridinium ion (C6H8N+) interacts with the tetrachlorocuprate anion through N—H⋯Cl and C—H(phenyl)⋯Cl contacts, forming a hydrogen-bonded layer-like structure. The supramolecular structure is further stabilized by C—H(methyl)⋯Cl interactions between the layers. |
| Databáze: | OpenAIRE |
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