Development of water-, oil-repellent and flame-retardant cotton fabrics by organic-inorganic hybrid materials
Autor: | Gulfem Mete, Nurhan Onar |
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Jazyk: | angličtina |
Rok vydání: | 2016 |
Předmět: |
Washing
Polymers and Plastics Polymers 02 engineering and technology Cotton 01 natural sciences Industrial and Manufacturing Engineering Contact angle Nanosols chemistry.chemical_compound Coating Dihydrogen phosphate Urea Composite material chemistry.chemical_classification Water–oil repellency Chelation Protective coatings Polymer 021001 nanoscience & nanotechnology 0210 nano-technology General Agricultural and Biological Sciences Hybrid material Oil repellency Fire retardant Materials science silanes Materials Science (miscellaneous) polymer Organic-inorganic hybrid materials Formaldehyde engineering.material 010402 general chemistry Cotton fabrics Flame retardants Tetra-ethyl-ortho-silicate organic-inorganic materials Cross linking agents Flame retardancy parasitic diseases Rolls (machine components) Flame retardant properties Tear resistance Crosslinking fungi technology industry and agriculture 0104 chemical sciences Metabolism chemistry Chemical engineering Polyvinyl acetates engineering Plastic coatings |
DOI: | 10.1080/00405000.2015.1128208 |
Popis: | In this study, water-repellent, oil-repellent and flame-retardant cotton fabrics were developed by solgel technique. With this aim, nanosols were prepared using tetraethylorthosilicate and hexadecyltrimethoxysilane as precursors, guanidine dihydrogen phosphate as flame-retardant agent and Guard AFB as conventional water–oil-repellent agent, solvents and chelating agents. Then, to AC105, VA7110, PU1110 and FC9005 as polymeric additives, with/without FX8000 or urea and formaldehyde as cross-linking agents, were added some nanosols to improve washing fastness of the fabric samples. Cotton fabrics were treated with nanosols without polymeric additives by pad–dry–cure process, while they were coated with nanosols containing polymeric additives by knife-over-roll coating. Water–oil-repellent properties, flame-retardant properties, washing fastness, contact angle, whiteness, tear strength and add-on values of the coated fabric samples were determined. It was found that the cotton fabrics with good water–oil-repellence and flame-retardant properties with relatively durable properties could be produced using nanosols containing guanidine dihydrogen phosphate and urea, together with tetraethylorthosilicate and hexadecyltrimethoxysilane as precursors, and lower concentrations of Guard AFB as commercial water–oil-repellent agent. However, the fabric samples were still not sufficiently durable when washed. It was deduced that the durability of cotton fabric during washing is developed by means of treatment with nanosols containing polyvinyl acetate-based polymer. © 2016 The Textile Institute. |
Databáze: | OpenAIRE |
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