Two‐Dimensional Metal–Organic Framework Nanosheets: Synthesis and Applications in Electrocatalysis and Photocatalysis

Autor: Ya‐Long Liu, Xiang‐Yue Liu, Li Feng, Lan‐Xing Shao, Si‐Jun Li, Jing Tang, Hu Cheng, Zhuo Chen, Rui Huang, Hai‐Chao Xu, Jin‐Liang Zhuang
Rok vydání: 2022
Předmět:
Zdroj: ChemSusChem. 15
ISSN: 1864-564X
1864-5631
DOI: 10.1002/cssc.202102603
Popis: Two-dimensional metal-organic nanosheets (2D MONs) are an emerging class of ultrathin, porous, and crystalline materials. The organic/inorganic hybrid nature offers MONs distinct advantages over other inorganic nanosheets in terms of diversity of organic ligands and metal notes. Compared to bulk three-dimensional metal-organic frameworks, 2D MONs possess merits of high density and readily accessible catalytic sites, reduced diffusion pathways for reactants/products, and fast electron transport. These features endow MONs with enhanced physical/chemical properties and are ideal for heterogeneous catalysis. In this Review, state-of-the-art synthetic methods for the fabrication of 2D MONs were summarized. The advances of 2D MONs-based materials for electrocatalysis and photocatalysis, including hydrogen evolution reaction (HER), oxygen evolution reaction (OER), oxygen reduction reaction (ORR), carbon dioxide reduction reaction (CO
Databáze: OpenAIRE
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