Solution-Synthesized Extended Graphene Nanoribbons Deposited by High-Vacuum Electrospray Deposition

Autor:	Sebastian Scherb, Antoine Hinaut, Xuelin Yao, Alicia Götz, Samir H. Al-Hilfi, Xiao-Ye Wang, Yunbin Hu, Zijie Qiu, Yiming Song, Klaus Müllen, Thilo Glatzel, Akimitsu Narita, Ernst Meyer
Rok vydání:	2022
Předmět:	General Engineering General Physics and Astronomy General Materials Science
Zdroj:	ACS Nano. 17:597-605
ISSN:	1936-086X 1936-0851
DOI:	10.1021/acsnano.2c09748
Popis:	Solution-synthesized graphene nanoribbons (GNRs) facilitate various interesting structures and functionalities, like nonplanarity and thermolabile functional groups, that are not or not easily accessible by on-surface synthesis. Here, we show the successful high-vacuum electrospray deposition (HVESD) of well-elongated solution-synthesized GNRs on surfaces maintained in ultrahigh vacuum. We compare three distinct GNRs, a twisted nonplanar fjord-edged GNR, a methoxy-functionalized "cove"-type (or also called gulf) GNR, and a longer "cove"-type GNR both equipped with alkyl chains on Au(111). Nc-AFM measurements at room temperature with submolecular imaging combined with Raman spectroscopy allow us to characterize individual GNRs and confirm their chemical integrity. The fjord-GNR and methoxy-GNR are additionally deposited on nonmetallic HOPG and SiO
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c108eda872ef489489e4f30e3bd4e6cf https://doi.org/10.1021/acsnano.2c09748 Zobrazit plný text záznamu