Synthesis of Functionalized Allylsilanes via the Condensation of α,β-Unsaturated Carbonyl Compounds with γ-Trimethylsilylmethylallylzircocene Followed by Anionic Oxy-Cope Rearrangement

Autor:	Xian Huang, Jin-Hong Pi
Rok vydání:	2003
Předmět:	chemistry.chemical_compound Cyclopentanol Chemistry Intramolecular force Polymer chemistry Organic Chemistry Condensation Organic chemistry Molecule Oxy-Cope rearrangement General Medicine Medicinal chemistry Carbonyl group
Zdroj:	Synlett. :2413-2415
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-2003-42126
Popis:	Condensation of α,β-unsaturated carbonyl compounds with y-trimethylsilylmethylallylzircocene followed by anionic oxy-Cope rearrangement provided a novel method for the synthesis of functionalized allylsilanes compounds possessing a carbonyl group in the same molecule, which are versatile intermediates for intramolecular allylsilylation, giving cyclopentanols on treatment with n-Bu 4 NF.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c10488be1fedd6a06608faa5d0ad7e09 https://doi.org/10.1055/s-2003-42126 Zobrazit plný text záznamu