Synthesis of Halide-Modulated Cuprous(I) Coordination Polymers with Mechanochromic and Photocatalytic Properties
| Autor: | Lan-Xia Hu, Shu-Mei Chen, Yao Kang, Tian Wen, Meiyan Gao |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Hydrogen bond Stacking Halide chemistry.chemical_element Polymer 010402 general chemistry Photochemistry 01 natural sciences Copper 0104 chemical sciences Inorganic Chemistry chemistry Halogen Photocatalysis Amine gas treating Physical and Theoretical Chemistry |
| Zdroj: | Inorganic chemistry. 56(11) |
| ISSN: | 1520-510X |
| Popis: | Two copper(I) halide-based coordination polymers, namely, [Cu3Cl2(Tipa)2]Cl (1, (Tipa = tris(4-(1H-imidazol-1-yl)phenyl)amine) and [Cu3I3(CuI)2(Tipa)3] (2), were obatined under the solvothermal reactions, respectively. Compound 1 with the chain structure shows unique Cu···Cu interactions, C–H···Cl halogen hydrogen bonds, and π···π stacking interactions. It also exhibits unusual mechanochromic and photocatalytic properties on degradation of methylene blue (MB). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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