A novel dimeric copper salicylate with an undissociated COOH group: Synthesis and crystal structure of [Cu2(HSal)(Sal)(2,2′-bpy)2](ClO4)
| Autor: | Ramaswamy Murugavel, Nallasamy Palanisami, Ganesan Prabusankar |
|---|---|
| Rok vydání: | 2006 |
| Předmět: |
Earth Metal-Ions
Stereochemistry Perchlorate Stacking Crystal structure Ligands Dihydrate Inorganic Chemistry chemistry.chemical_compound Deprotonation Complexes Polymer chemistry Acid Materials Chemistry Molecule 1 10-Phenanthroline Physical and Theoretical Chemistry Copper Salicylate Hydrogen bond Architectures Hydrogen Bonding Coordination Polymers Fluorescence Copper salicylate chemistry Crystal Structure |
| Zdroj: | Inorganic Chemistry Communications. 9:1002-1006 |
| ISSN: | 1387-7003 |
| DOI: | 10.1016/j.inoche.2006.05.025 |
| Popis: | A dinuclear copper salicylate [Cu-2(HSal)(Sal)(2,2'-bpy)(2)](ClO4) (1) (H(2)Sal = salicylic acid) has been synthesized and characterized with the aid of elemental analysis and infrared, ultraviolet and fluorescence spectroscopic studies. The molecular structure of 1, determined by single-crystal X-ray diffraction studies, shows the presence of incompletely deprotonated salicylate ligands in the complex. Hydrogen bonding interactions and pi-pi aromatic stacking lead to the formation of 2D polymeric structure in the solid state. (C) 2006 |
| Databáze: | OpenAIRE |
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