Silver or cerium-promoted free radical cascade difunctionalization of o-vinylanilides with sodium aryl- or alkylsulfinates

Autor:	Jilai Wu, Yuanyuan Zong, Jincan Zhao, Yaxin Ge, Qinqin Yan, Lixian Sun, Chunxia Zhao, Yiming Li, Zejiang Li
Rok vydání:	2019
Předmět:	010405 organic chemistry Aryl Sodium Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences Biochemistry Combinatorial chemistry 0104 chemical sciences chemistry.chemical_compound Cerium chemistry Cascade Reaction system Physical and Theoretical Chemistry
Zdroj:	Organic & Biomolecular Chemistry. 17:794-797
ISSN:	1477-0539 1477-0520
DOI:	10.1039/c8ob02964d
Popis:	An efficient cascade oxysulfonylation of o-vinylanilides with sodium aryl- or alkylsulfinates by a free radical mechanism has been developed, which provides a mild, facile and convenient method for the synthesis of various benzoxazines. Control experiments, including gram-level reactions and mechanistic studies, are involved in the reaction system.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bff9a2ffe217f282189b0f0791403486 https://doi.org/10.1039/c8ob02964d Zobrazit plný text záznamu