Atomic layer deposition of Nb-doped TiO2: Dopant incorporation and effect of annealing

Autor: Wilhelmus M. M. Kessels, Wilhelmus J. H. Berghuis, Jimmy Melskens, Marcel A. Verheijen, Bart Macco, Saravana Balaji Basuvalingam
Přispěvatelé: Plasma & Materials Processing, Atomic scale processing, Processing of low-dimensional nanomaterials, EIRES
Rok vydání: 2020
Předmět:
Zdroj: Journal of Vacuum Science and Technology A: Vacuum, Surfaces, and Films, 38(2):022408. AVS Science and Technology Society
ISSN: 1520-8559
0734-2101
Popis: Transparent conductive oxides form an important group of materials that combine high conductivity with high transparency. In this context, the authors designed an atomic layer deposition process for Nb-doped TiO2. The presented process enables accurate control over both the position and concentration of the Nb dopants. The as-deposited films become crystalline (brookite) and low resistive (4.3 × 10−3 Ω cm) upon a postdeposition anneal with temperatures as low as 300 °C. Variations in annealing ambient and temperature yielded resistivity changes over four orders of magnitude and significant changes in the sub-bandgap absorption of light. Next to doping, annealing is therefore shown to be a powerful tool in controlling electrical and optical properties of TiO2:Nb.
Databáze: OpenAIRE