Hierarchical organization from self-assembling disulfide macrocycles
| Autor: | V. Haridas, Srikanta Sahu, Appa Rao Sapala |
|---|---|
| Rok vydání: | 2012 |
| Předmět: |
Macrocyclic Compounds
Rhodamines Chemistry Stereochemistry Metals and Alloys Disulfide bond Cystine General Chemistry Combinatorial chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Congo red chemistry.chemical_compound Self assembling Materials Chemistry Ceramics and Composites Rhodamine B Disulfides |
| Zdroj: | Chemical Communications. 48:3821 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c2cc30337j |
| Popis: | We report cystine-based macrocyclic compounds showing very unique self-assembling behavior. 24-membered disulfide macrocycle 3 shows a helical and tubular organization and also forms an insoluble plaque that is birefringent with congo red dye. 48-membered macrocycle 4 shows a vesicle-like assembly with capability for encapsulation, as demonstrated by rhodamine B encapsulation. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|