Preparation and Characterization of Polyester Polyol Modified Bitumen for Pavement Applications
Autor: | Serenay Akyol, Muzaffer Yasar, Ramazan Oguz Caniaz, Ziya Kostereli, metin sormagir, Savas Gurdal, Emel Baskent, Serhat Arca, Gülşen Albayrak Arı, Elif Kocaman, Refika Cetintas |
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Předmět: |
chemistry.chemical_classification
Adipic acid Materials science Softening point 0211 other engineering and technologies 02 engineering and technology General Medicine 021001 nanoscience & nanotechnology PET waste Polymer modified bitumen Polyester chemistry.chemical_compound chemistry Rheology Polyol Chemical engineering Asphalt 021105 building & construction Polyethylene terephthalate Plastic waste 0210 nano-technology |
Zdroj: | Volume: 19, Issue: 3 574-584 Eskişehir Technical University Journal of Science and Technology A-Applied Sciences and Engineering |
ISSN: | 2667-4211 |
Popis: | In this study, polymer modified bitumen (PMB) from polyester polyols was prepared by bis(2-hydroxyethyl terephthalate) (BHET) which was obtained by glycolysis of Polyethylene terephthalate (PET) waste. The effect of polyester polyol structure on the rheological properties of PMB was investigated. Polyester polyols obtained by the reaction of various polyols and polycarboxylic acids. POL1, synthesized from BHET and adipic acid (AA), were blended with the bitumen resulting in improved stiffness, rutting resistance and fatigue performance with respect to neat bitumen. Also, the synergistic effects of the polyester polyol addition into styrene-butadiene-styrene modified bitumen (SBS-Bitumen) were investigated where this reference mixture contains SBS loading of 3 % according to the weight of bitumen. Although the addition of POL1(1.3:1) into SBS:Bitumen mixture at 3:3:94 weight ratio didn’t alter the high temperature performance grade of PMB, POL1:SBS:Bitumen exhibited higher softening point, elastic recovery and rutting parameter than reference mixture. The early stage promising results of this study indicated the potential benefits of polyester polyol as bitumen modifier. Also, this study showed that the use of BHET obtained by PET waste as a starting material for polyester polyol synthesis could be an alternative way to utilize plastic waste. |
Databáze: | OpenAIRE |
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