Synthesis and structure characterization of a stable nonatwistacene
Autor: | Shuzhou Li, Hieu M. Duong, Fred Wudl, Xue-Wei Liu, Jan Ma, Gang Li, Jinchong Xiao, Yi Liu, Li Ji, Qichun Zhang, Wenxiong Shi |
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Přispěvatelé: | School of Materials Science & Engineering, School of Physical and Mathematical Sciences |
Jazyk: | angličtina |
Rok vydání: | 2012 |
Předmět: | |
Popis: | A clean reaction strategy based on thermally eliminating lactam bridges from a soluble acene precursor through a retro-Diels–Alder reaction, led to the synthesis and characterization of a novel, stable, green crystalline 6,8,10,17,19,21-hexaphenyl-1.22,4.5,11.12,15.16-tetrabenzononatwistacene. An analysis of the single crystal structure of the nonatwistacene indicates that this molecule is twisted at an angle of 25.44°. |
Databáze: | OpenAIRE |
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