Synthesis and structure characterization of a stable nonatwistacene

Autor:	Shuzhou Li, Hieu M. Duong, Fred Wudl, Xue-Wei Liu, Jan Ma, Gang Li, Jinchong Xiao, Yi Liu, Li Ji, Qichun Zhang, Wenxiong Shi
Přispěvatelé:	School of Materials Science & Engineering, School of Physical and Mathematical Sciences
Jazyk:	angličtina
Rok vydání:	2012
Předmět:	Chemistry Polymer chemistry Organic chemistry General Chemistry General Medicine Science::Chemistry [DRNTU] Retro-Diels–Alder reaction Catalysis Characterization (materials science)
Popis:	A clean reaction strategy based on thermally eliminating lactam bridges from a soluble acene precursor through a retro-Diels–Alder reaction, led to the synthesis and characterization of a novel, stable, green crystalline 6,8,10,17,19,21-hexaphenyl-1.22,4.5,11.12,15.16-tetrabenzononatwistacene. An analysis of the single crystal structure of the nonatwistacene indicates that this molecule is twisted at an angle of 25.44°.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bf25bb0ce21ad92490ee86729c11b514 http://hdl.handle.net/10220/12495 Zobrazit plný text záznamu