Addition of aluminium, zinc and magnesium hydrides to rhodium( iii )
| Autor: | Olga Ekkert, Andrew J. P. White, Harold Toms, Mark R. Crimmin |
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| Přispěvatelé: | The Royal Society, Engineering & Physical Science Research Council (EPSRC), Commission of the European Communities |
| Jazyk: | angličtina |
| Předmět: |
Chemistry
Multidisciplinary Inorganic chemistry DIHYDROGEN COMPLEXES chemistry.chemical_element 010402 general chemistry 01 natural sciences Reductive elimination Rhodium ACTIVATION Elimination reaction chemistry.chemical_compound RUTHENIUM COMPLEXES SIGMA-BOND Molecule Sigma bond AL-H COORDINATION Science & Technology 010405 organic chemistry Chemistry Bridging ligand General Chemistry SILANE 3. Good health 0104 chemical sciences Crystallography Physical Sciences X-RAY Dihydrogen complex Triethylsilane MOLECULAR-STRUCTURE BETA-DIKETIMINATE |
| Zdroj: | Chemical Science |
| ISSN: | 2041-6539 2041-6520 |
| DOI: | 10.1039/c5sc01309g |
| Popis: | We report the addition of M–H bonds (M = Al, Zn, Mg) to a Rh(iii) intermediate generated from the reductive elimination of triethylsilane from [Cp*Rh(H)2(SiEt3)2]. We report the addition of M–H bonds (M = Al, Zn, Mg) to a Rh(iii) intermediate generated from the reductive elimination of triethylsilane from [Cp*Rh(H)2(SiEt3)2]. A series of new heterobimetallic complexes possessing Rh–M bonds have been isolated and characterised by a number of spectroscopic (1H, 29Si, 13C, 103Rh NMR, infrared, and X-ray diffraction) and computational techniques (NBO and QTAIM analysis). Experimental and computational data are consistent with cleavage of the M–H bond upon addition to rhodium with formation of new Rh–M and Rh–H bonds. Upon photolysis the Al analogue of this series undergoes a further elimination reaction producing triethylsilane and a highly unusual Rh2Al2H4 containing cluster proposed to contain an Al(i) bridging ligand. |
| Databáze: | OpenAIRE |
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