Acetone-Based Cellulose Solvent
| Autor: | Tim Liebert, Marc Kostag, Thomas Heinze |
|---|---|
| Rok vydání: | 2014 |
| Předmět: |
Polymers and Plastics
Polymers Inorganic chemistry Salt (chemistry) engineering.material Chloride Acetone chemistry.chemical_compound Materials Chemistry medicine Cellulose Dissolution chemistry.chemical_classification Viscosity Organic Chemistry Chemical modification Hydrogen Bonding Quaternary Ammonium Compounds Solvent chemistry Solvents engineering Biopolymer medicine.drug |
| Zdroj: | Macromolecular Rapid Communications. 35:1419-1422 |
| ISSN: | 1022-1336 |
| Popis: | Acetone containing tetraalkylammonium chloride is found to be an efficient solvent for cellulose. The addition of an amount of 10 mol% (based on acetone) of well-soluble salt triethyloctylammonium chloride (Et3 OctN Cl) adjusts the solvent's properties (increases the polarity) to promote cellulose dissolution. Cellulose solutions in acetone/Et3 OctN Cl have the lowest viscosity reported for comparable aprotic solutions making it a promising system for shaping processes and homogeneous chemical modification of the biopolymer. Recovery of the polymer and recycling of the solvent components can be easily achieved. |
| Databáze: | OpenAIRE |
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