Supercapacitive paper based microbial fuel cell: High current/power production within a low cost design

Autor: Jonathan Winfield, Ioannis Ieropoulos, Pavlina Theodosiou, Carlo Santoro
Přispěvatelé: Santoro, C, Winfield, J, Theodosiou, P, Ieropoulos, I
Rok vydání: 2019
Předmět:
Zdroj: Santoro, C, Winfield, J, Theodosiou, P & Ieropoulos, I 2019, ' Supercapacitive paper based microbial fuel cell: High current/power production within a low cost design ', Bioresource Technology Reports, vol. 7, 100297 . https://doi.org/10.1016/j.biteb.2019.100297
Bioresource Technology Reports
ISSN: 2589-014X
DOI: 10.1016/j.biteb.2019.100297
Popis: Microbial fuel cells (MFCs) with paper separators and liquid containing elements were investigated in supercapacitive mode. MFCs (15 mL) in a supercapacitive configuration, consisted of plain wrapped carbon veil anode (negative) and conductive latex cathode (positive). The internal supercapacitor is discharged galvanostatically and is self-recharged as red-ox reactions occur on both electrodes. MFCs were discharged at different current pulses varying from 1 mA to 7 mA. The MFCs had an equivalent series resistance of 41.2 ± 3.5 Ω caused mainly by the cathode. A maximum power of 1.380 ± 0.083 mW (0.092 ± 0.006 mW mL−1) was measured. Durability tests were conducted over 24 h collecting 1000 discharge cycles (0.5 s) and self-recharges (85 s) at a current of 1 mA. Over time the anode potential dropped causing a decline in performance perhaps due to evaporation of liquid from the pyramidal structure. Resistance and apparent capacitance measured during the durability test remained approximately constant during the cycles.
Graphical abstract Unlabelled Image
Highlights • Supercapacitor paper-based MFCs are reported for the first time. • Galvanostatic discharges at different current pulses (1 mA to 7 mA) were analysed. • Equivalent series resistance (ESR) and apparent capacitance (C) were identified. • Maximum power achieved was 1.380 ± 0.083 mW (0.092 ± 0.006 mW mL−1). • The system stability was investigated through 1000 discharge/self-recharge cycles.
Databáze: OpenAIRE