Synthesis and X-ray crystal structure of a bis-cyclometalated phosphorescent red-emitting iridium(III) complex

Autor:	Manuel Thesen, Karlheinz Sünkel, Peter Mayer, Marion Graf, Hartmut Krüger
Přispěvatelé:	Publica
Rok vydání:	2009
Předmět:	Chemistry Ligand X-ray chemistry.chemical_element Crystal structure Chloride Inorganic Chemistry Crystallography Materials Chemistry medicine Iridium Emission spectrum Physical and Theoretical Chemistry Absorption (chemistry) Phosphorescence medicine.drug
Zdroj:	Inorganic Chemistry Communications. 12:701-703
ISSN:	1387-7003
Popis:	The synthesis of the bis-cyclometalated complex [{Ir(μ-Cl)(ccpz)2}2] (1, cppz = 1-chloro-4-(4-chlorophenyl)-phthalazine) from hydrated iridium(III) chloride and the ligand ccpz in refluxing ethoxyethanol is described. Compound 1 was characterized by spectroscopic means and the crystal structure was determined by X-ray crystallography. The absorption and emission spectra exhibit the new compound as a red-emitting phosphorescent complex.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bdc502080a91e519af04c917b549eda4 https://doi.org/10.1016/j.inoche.2009.05.017 Zobrazit plný text záznamu Full Text from ScienceDirect