Sono-Cavitation and Nebulization-Based Synthesis of Conjugated Microporous Polymers for Energy Storage Applications

Autor:	Deok-Ho Roh, HyeonOh Shin, Hyun-Tak Kim, Tae-Hyuk Kwon
Rok vydání:	2021
Předmět:	General Materials Science
Zdroj:	ACS Applied Materials & Interfaces. 13:61598-61609
ISSN:	1944-8252 1944-8244
Popis:	Conjugated microporous polymers (CMPs) are promising energy storage materials owing to their rigid and cross-linked microporous structures. However, the fabrication of nano- and microstructured CMP films for practical applications is currently limited by processing challenges. Herein, we report that combined sono-cavitation and nebulization synthesis (SNS) is an effective method for the synthesis of CMP films from a monomer precursor solution. Using the SNS, the scalable fabrication of microporous and redox-active CMP films can be achieved via the oxidative C-C coupling polymerization of the monomer precursor. Intriguingly, the ultrasonic frequency used during SNS strongly affects the synthesis of the CMP films, resulting in an approximately 30% improvement in reaction yields and ca. 1.3-1.7-times enhanced surface areas (336-542 m
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bd9f758079ded78b14ac099a77a71a75 https://doi.org/10.1021/acsami.1c13755 Zobrazit plný text záznamu