Molecular Intermediate in the Directed Formation of a Zeolitic Metal–Organic Framework

Autor:	May Nyman, Mark E. Bowden, Dushyant Barpaga, Yi Han, Wenqian Xu, Praveen K. Thallapally, Lili Liu, Michael A. Sinnwell, Sanjit Ghose, Quin R. S. Miller, Maria L. Sushko, Lauren Palys, H. Todd Schaef
Rok vydání:	2020
Předmět:	Small-angle X-ray scattering General Chemistry 010402 general chemistry 01 natural sciences Biochemistry Combinatorial chemistry Catalysis 0104 chemical sciences chemistry.chemical_compound Colloid and Surface Chemistry chemistry Sodalite Imidazole Metal-organic framework Topology (chemistry)
Zdroj:	Journal of the American Chemical Society. 142:17598-17606
ISSN:	1520-5126 0002-7863
DOI:	10.1021/jacs.0c07862
Popis:	Directed synthesis promises control over architecture and function of framework materials. In practice, however, designing such syntheses requires a detailed understanding of the multistep pathways of framework formations, which remain elusive. By identifying intermediate coordination complexes, this study provides insights into the complex role of a structure-directing agent (SDA) in the synthetic realization of a promising material. Specifically, a novel molecular intermediate was observed in the formation of an indium zeolitic metal-organic framework (ZMOF) with a sodalite topology. The role of the imidazole SDA was revealed by time-resolved in situ powder X-ray diffraction (XRD) and small-angle X-ray scattering (SAXS).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bd85b7e935535384918ee36a338d36d2 https://doi.org/10.1021/jacs.0c07862 Zobrazit plný text záznamu