Degradable copolymers with incorporated ester groups by radical ring-opening polymerization using atom transfer radical polymerization
| Autor: | Antonina Simakova, Caroline Arnoux, Krzysztof Matyjaszewski |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Materials science
Polymers and Plastics Atom-transfer radical-polymerization General Chemical Engineering Radical polymerization Chain transfer 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences Article 0104 chemical sciences Living free-radical polymerization Cobalt-mediated radical polymerization Polymerization Catalytic chain transfer Polymer chemistry Materials Chemistry Reversible addition−fragmentation chain-transfer polymerization 0210 nano-technology |
| Zdroj: | Polimery. 62:262-271 |
| ISSN: | 0032-2725 |
| Popis: | Preparation of degradable materials using reversible deactivation radical polymerizations (RDRP) is of particular interest for biomedical applications. In this paper we report preparation of degradable copolymers of 2-methylene-4-phenyl-1, 3-dioxolane (MPDL), monomer which undergoes ring-opening reaction and forms ester bond upon radical polymerization, with hydrophobic and hydrophilic methacrylate monomers using atom transfer radical polymerization (ATRP). Copolymers composition and degradation were evaluated upon varied temperature and monomer type. |
| Databáze: | OpenAIRE |
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