Mixtures of chiral and achiral monodentate ligands in asymmetric Rh-catalyzed olefin hydrogenation: reversal of enantioselectivity

Autor:	Manfred T. Reetz, Gerlinde Mehler
Rok vydání:	2003
Předmět:	Olefin fiber Denticity Chemistry Organic Chemistry Enantioselective synthesis chemistry.chemical_element General Medicine Biochemistry Combinatorial chemistry Catalysis Rhodium Transition metal Polymer chemistry Drug Discovery Organic chemistry
Zdroj:	Tetrahedron Letters. 44:4593-4596
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(03)00976-6
Popis:	The recently described method of combinatorial asymmetric transition metal catalysis based on the use of mixtures of chiral monodentate P-ligands has been extended to include mixtures of chiral and achiral monodentate P-ligands, reversal of enantioselectivity in Rh-catalyzed olefin hydrogenation being possible in appropriate cases.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bd51686a1d3ad243e9d18b7281de1317 https://doi.org/10.1016/s0040-4039(03)00976-6 Zobrazit plný text záznamu Full Text from ScienceDirect