Organic Thin-Film-Transistor Au/Poly(3-hexylthiophene)/(Bilayer Dielectrics)/Si Having Carbon Nanotubes Chemically Bonded to Poly(3-hexylthiophene) in the Active Layer
| Autor: | Jeng Rong Ho, Fang Chi Li, Je Yuan Yeh, Raymond Chien-Chao Tsiang, Ying Shiun Chou, Shin Chi Tsai, Cheng Yang Yeh |
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| Rok vydání: | 2014 |
| Předmět: | |
| Zdroj: | Journal of Nanoscience and Nanotechnology. 14:5019-5027 |
| ISSN: | 1533-4899 1533-4880 |
| DOI: | 10.1166/jnn.2014.9259 |
| Popis: | Using poly(3-hexylthiophene) (P3HT) covalently bonded with carbon nanotubes (CNT) as an active layer in a bottom-gate/top contact, Au/(P3HT)/(bilayer dielectric)/Si OTFT device has resulted in an enhanced charge transport. The CNTs were firstly functionalized via ligand exchange with ferrocene, next lithiated by sec-butyllithium (s-BuLi) and then linked anionically with P3HT which has been synthesized via the modified Grignard metathesis method. Compared to the pristine P3HT, the CNTs-containing P3HT composite material has a higher energy level of HOMO and a smaller electrochemical bandgap E(g)(chem). The smaller bandgap enhances the charge carrier transport and the higher HOMO energy level indicates a reduced barrier and an increased injection rate for charge carriers at the source contact. Furthermore, the threshold voltage V(T) of CNTs-containing P3HT samples is lower and its saturation current I(D) and the the field-effect mobility are higher. An OTFT device fabricated with such a composite sample containing 1.16% CNTs has a carrier mobility and saturation current three to five times higher than pristine P3HT. |
| Databáze: | OpenAIRE |
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